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Asymmetric Synthetic Access to the Hetisine Alkaloids: Total Synthesis of (+)-Nominine
A dual cycloaddition strategy for the synthesis of the hetisine alkaloids has been developed, illustrated by a concise asymmetric total synthesis of (+)-nominine (7). The approach relies on an early-stage intramolecular 1,3-dipolar cycloaddition of a 4-oxido-isoquinolinium betaine dipole with an ene...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2648811/ https://ncbi.nlm.nih.gov/pubmed/18046691 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.200701290 |
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