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Deconstructive Asymmetric Total Synthesis of Morphine-Family Alkaloid (−)-Thebainone A
Herein, we describe the development of a deconstructive strategy for the first asymmetric synthesis of (−)-thebainone A, capitalized on an enantioselective C−C bond activation and a C−O bond cleavage reaction. The Rh-catalyzed asymmetric ‘cut-and-sew’ transformation between sterically hindered trisu...
Tallennettuna:
| Julkaisussa: | Angew Chem Int Ed Engl |
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| Päätekijät: | , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2021
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8159902/ https://ncbi.nlm.nih.gov/pubmed/33822455 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202103553 |
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