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On the Mechanism of Nitrosoarene-Alkyne Cycloaddition

The thermal reaction between nitrosoarenes and alkynes produces N-hydroxyindoles as the major products. The mechanism of these novel reactions has been probed using a combination of experimental and computational methods. The reaction of nitrosobenzene (NB) with an excess of phenyl acetylene (PA) is...

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Detalhes bibliográficos
Main Authors: Penoni, Andrea, Palmisano, Giovanni, Zhao, Yi-Lei, Houk, Kendall N., Volkman, Jerome, Nicholas, Kenneth M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2646788/
https://ncbi.nlm.nih.gov/pubmed/19093864
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja806715u
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