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Reaction of Isonitriles with Carboxylic Acids in a Cavitand: Observation of Elusive Isoimide Intermediates

[Image: see text] A deep cavitand with an inwardly-directed carboxylic acid function reacts with small aliphatic isonitriles to form N-acyl formamides inside the cavity. The unique isolation and stabilization of covalently bound guests within the structured environment of the cavitand allows for obs...

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Библиографические подробности
Главные авторы: Restorp, Per, Rebek, Julius
Формат: Artigo
Язык:Inglês
Опубликовано: 2008
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC2642476/
https://ncbi.nlm.nih.gov/pubmed/18698780
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja803854r
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