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Reaction of Isonitriles with Carboxylic Acids in a Cavitand: Observation of Elusive Isoimide Intermediates
[Image: see text] A deep cavitand with an inwardly-directed carboxylic acid function reacts with small aliphatic isonitriles to form N-acyl formamides inside the cavity. The unique isolation and stabilization of covalently bound guests within the structured environment of the cavitand allows for obs...
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| Autori principali: | , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2008
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2642476/ https://ncbi.nlm.nih.gov/pubmed/18698780 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja803854r |
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