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Hydrogen Atom Transfer Reactions of a Ruthenium Imidazole Complex: Hydrogen Tunneling and the Applicability of the Marcus Cross Relation
The reaction of Ru(II)(acac)(2)(py-imH) (Ru(II)imH) with TEMPO(•) (2,2,6,6-tetramethyl-piperidine-1-oxyl radical) in MeCN quantitatively gives Ru(III)(acac)(2)(py-im) (Ru(III)im) and the hydroxylamine TEMPO-H by transfer of H(•) (H(+) + e(−)) (acac = 2,4-pentanedionato, py-imH = 2-(2′-pyridyl)imidaz...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2008
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2633126/ https://ncbi.nlm.nih.gov/pubmed/18841973 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja805067h |
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