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A Novel Synthetic Route to 3-Sulfenyl- and 3-Selenylindoles by n-Bu(4)NI-Induced Electrophilic Cyclization

[Image: see text] 3-Sulfenyl- and 3-selenylindoles are prepared in excellent yields by the palladium/copper-catalyzed crossing coupling of N,N-dialkyl-ortho-iodoanilines and terminal alkynes, followed by electrophilic cyclization with arylsulfenyl chlorides and arylselenyl chlorides in the presence...

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Hlavní autoři: Chen, Yu, Cho, Chul-Hee, Larock, Richard C.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2631273/
https://ncbi.nlm.nih.gov/pubmed/19046068
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8021287
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