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Energetics of an n→π(*) Interaction that Impacts Protein Structure
[Figure: see text] The trans/cis ratio of the amide bond in N-formylproline phenylesters correlates with electron-withdrawal by a para substituent. The slope of the Hammett plot (ρ = 0.26) is indicative of a substantial effect. This effect arises from a favorable n→π(*) interaction between the amide...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2625295/ https://ncbi.nlm.nih.gov/pubmed/17020280 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol061569t |
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