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Synthesis of a β-(1→3)-d-Rhamnotetraose by a One-Pot, Multiple Radical Fragmentation
A naturally-occurring β-(1→3)-d-rhamnotetraose has been constructed under conditions of sequential β -selective mannosylation controlled by the 4,6-O-[1-cyano-2-(2-iodophenyl)-ethylidene] protecting group. The route is concise, proceeding through a late stage radical deoxygenation that successfully...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2617736/ https://ncbi.nlm.nih.gov/pubmed/16956218 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol061706m |
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