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4,6-O-[1-Cyano-2-(2-iodophenyl)ethylidene] Acetals. Improved Second Generation Acetals for the Stereoselective Formation of β-d-Mannopyranosides and Regioselective Reductive Radical Fragmentation to β-d-Rhamnopyranosides. Scope and Limitations
The [1-cyano-2-(2-iodophenyl)]ethylidene group is introduced as an acetal protecting group for carbohydrate thioglycoside donors. The group is easily introduced under mild conditions, over short reaction times, and in presence of a wide variety of other protecting groups by the reaction of the 4,6-d...
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| Publicado no: | J Org Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4664482/ https://ncbi.nlm.nih.gov/pubmed/16626126 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo0526688 |
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