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A Rapid, One-Pot Synthesis of β-Siloxy-α-Haloaldehydes
The Mukaiyama cross aldol reaction of α-fluoro-, α-chloro-, and α-bromoacetaldehyde-derived (Z)-tris(trimethylsilyl)- silyl enol ethers furnishing anti-β-siloxy-α-haloaldehydes is described. A highly diastereoselective, one-pot, sequential double aldol process, affording novel β,δ-bissiloxy-α,γ-bish...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3181128/ https://ncbi.nlm.nih.gov/pubmed/21815682 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2066169 |
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