The change in hydrogen bond strength accompanying charge rearrangement: Implications for enzymatic catalysis
The equilibrium for formation of the intramolecular hydrogen bond (K(HB)) in a series of substituted salicylate monoanions was investigated as a function of ΔpK(a), the difference between the pK(a) values of the hydrogen bond donor and acceptor, in both water and dimethyl sulfoxide. The dependence o...
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| Izdano u: | Proc Natl Acad Sci U S A |
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| Glavni autori: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
National Academy of Sciences
1996
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC26157/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/8962076/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.93.25.14474 |
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