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The change in hydrogen bond strength accompanying charge rearrangement: Implications for enzymatic catalysis
The equilibrium for formation of the intramolecular hydrogen bond (K(HB)) in a series of substituted salicylate monoanions was investigated as a function of ΔpK(a), the difference between the pK(a) values of the hydrogen bond donor and acceptor, in both water and dimethyl sulfoxide. The dependence o...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The National Academy of Sciences of the USA
1996
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC26157/ https://ncbi.nlm.nih.gov/pubmed/8962076 |
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