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Intramolecular Homolytic Aromatic Substitution of Alkyl 2-Benzimidazolyl Sulfones as a Means of Entry into Alkyl Radicals for Organic Synthesis

The intramolecular radical aromatic substitution of heteroaryl sulfones by tethered aryl radicals has been investigated as a source of alkyl radicals. The 1-(2-iodobenzyl)benzimidazole-2-sulfonyl system was found to be the most effective, while a tetrazole-based system did not undergo the desired ra...

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Detalhes bibliográficos
Main Authors: Crich, David, Grant, Daniel
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2615488/
https://ncbi.nlm.nih.gov/pubmed/19404382
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2008.02.174
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