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Application of the Rh(ll)-Cyclization/Cycloaddition Cascade for the Total Synthesis of (±)-Aspidophytine
A new strategy for the synthesis of (±)-aspidophytine has been developed and is based on a Rh(ll)-catalyzed cyclization/dipolar-cycloaddition sequence. The resulting [3+2]-cycloadduct undergoes an efficient Lewis acid mediated cascade that rapidly provides the complete skeleton of aspidophytine. The...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2006
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2604816/ https://ncbi.nlm.nih.gov/pubmed/16836384 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol061137i |
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