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Asymmetric Synthesis of Ring Functionalized trans-2,6-Disubstituted Piperidines from N-Sulfinyl δ-Amino β-Keto Phosphonates. Total Synthesis of (−)-Myrtine
Sulfinimine-derived N-sulfinyl δ-amino β-ketophosphonates are transformed via the enaminone to the phosphoryl dihydropyridones that selectively give trans-2,6-disubstituted 1,2,5,6-tetrahydropyridines on organocuprate addition and dephosphorylation.
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2597462/ https://ncbi.nlm.nih.gov/pubmed/17305397 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo062365t |
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