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Resolution of multiple substrate binding sites in cytochrome P450 3A4: the stoichiometry of the enzyme-substrate complexes probed by FRET and Job’s titration

To explore the mechanism of homotropic cooperativity in human cytochrome P450 3A4 (CYP3A4) we studied the interactions of the enzyme with 1-pyrenebutanol (1-PB), 1- pyrenemethylamine (PMA), and bromocriptine by FRET from the substrate fluorophore to the heme, and by absorbance spectroscopy. These ap...

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Detalhes bibliográficos
Main Authors: Fernando, Harshica, Halpert, James R., Davydov, Dmitri R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2596942/
https://ncbi.nlm.nih.gov/pubmed/16566594
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi052491b
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