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Stereoselective Epoxidation of 4-Deoxypentenosides: A Polarized-πModel
The high facioselectivity in the epoxidation of 4-deoxypentenosides (4-DPs) by dimethyldioxirane (DMDO) correlates with a stereoelectronic bias in the 4-DPs’ ground-state conformations, as elucidated by polarized-π frontier molecular orbital (PPFMO) analysis.
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2596068/ https://ncbi.nlm.nih.gov/pubmed/16986946 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0617401 |
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