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Sulfoxide as a Ligand in Iron(II) Porphyrinates: S– or O–Bound?

In order to study the bonding of sulfoxides to iron(II) porphyrinates, an equilibrium study of Fe(TPP) with tetramethylenesulfoxide (TMSO) has been performed. UV-vis spectra at different concentrations of TMSO have shown distinct character belonging to three species: four-coordinate Fe(II)(TPP), fiv...

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Hlavní autoři: Hu, Chuanjiang, Noll, Bruce, Scheidt, W. Robert
Médium: Artigo
Jazyk:Inglês
Vydáno: 2007
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2593864/
https://ncbi.nlm.nih.gov/pubmed/17824697
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic7008495
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