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Sulfoxide as a Ligand in Iron(II) Porphyrinates: S– or O–Bound?
In order to study the bonding of sulfoxides to iron(II) porphyrinates, an equilibrium study of Fe(TPP) with tetramethylenesulfoxide (TMSO) has been performed. UV-vis spectra at different concentrations of TMSO have shown distinct character belonging to three species: four-coordinate Fe(II)(TPP), fiv...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2593864/ https://ncbi.nlm.nih.gov/pubmed/17824697 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic7008495 |
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