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The ferritin Fe2 site at the diiron catalytic center controls the reaction with O(2) in the rapid mineralization pathway
Oxidoreduction in ferritin protein nanocages occurs at sites that bind two Fe(II) substrate ions and O(2), releasing Fe(III)(2)–O products, the biomineral precursors. Diferric peroxo intermediates form in ferritins and in the related diiron cofactor oxygenases. Cofactor iron is retained at diiron si...
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
National Academy of Sciences
2008
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2587572/ https://ncbi.nlm.nih.gov/pubmed/19011101 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0805083105 |
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