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The ferritin Fe2 site at the diiron catalytic center controls the reaction with O(2) in the rapid mineralization pathway

Oxidoreduction in ferritin protein nanocages occurs at sites that bind two Fe(II) substrate ions and O(2), releasing Fe(III)(2)–O products, the biomineral precursors. Diferric peroxo intermediates form in ferritins and in the related diiron cofactor oxygenases. Cofactor iron is retained at diiron si...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Tosha, Takehiko, Hasan, Mohammad R., Theil, Elizabeth C.
Format: Artigo
Sprache:Inglês
Veröffentlicht: National Academy of Sciences 2008
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2587572/
https://ncbi.nlm.nih.gov/pubmed/19011101
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0805083105
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