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Total Synthesis of (±)-Strychnine via a [4+2]-Cycloaddition/Rearrangement Cascade
A new strategy for the synthesis of the Strychnos alkaloid (±)-strychnine has been developed and is based on an intramolecular [4+2]-cycloaddition/rearrangement cascade of an indolyl substituted amidofuran. The critical D-ring was assembled by an intramolecular palladium catalyzed enolate-driven cro...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2007
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2587098/ https://ncbi.nlm.nih.gov/pubmed/17217284 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol062728b |
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