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Orthogonal dipolar interactions between amide carbonyl groups

Orthogonal dipolar interactions between amide C=O bond dipoles are commonly found in crystal structures of small molecules, proteins, and protein–ligand complexes. We herein present the experimental quantification of such interactions by employing a model system based on a molecular torsion balance....

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Detalhes bibliográficos
Main Authors: Fischer, Felix R., Wood, Peter A., Allen, Frank H., Diederich, François
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2582285/
https://ncbi.nlm.nih.gov/pubmed/18981424
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0806129105
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