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Relative orientation of the carbonyl groups determines the nature of orbital interactions in carbonyl–carbonyl short contacts

Carbonyl–carbonyl (CO···CO) interactions are emerging noncovalent interactions found in many small molecules, polyesters, peptides and proteins. However, little is known about the effect of the relative orientation of the two carbonyl groups on the nature of these interactions. Herein, we first show...

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Publicado en:Chem Sci
Autores principales: Sahariah, Biswajit, Sarma, Bani Kanta
Formato: Artigo
Lenguaje:Inglês
Publicado: Royal Society of Chemistry 2018
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6346288/
https://ncbi.nlm.nih.gov/pubmed/30774885
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04221g
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