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Total Synthesis, Structure Revision, and Absolute Configuration of (−)-Brevenal

Total synthesis of structure 1 originally proposed for brevenal, a nontoxic polycyclic ether natural product isolated from the Florida red tide dinoflagellate, Karenia brevis, was accomplished. The key features of the synthesis involved (i) convergent assembly of the pentacyclic polyether skeleton b...

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Detalhes bibliográficos
Main Authors: Fuwa, Haruhiko, Ebine, Makoto, Bourdelais, Andrea J., Baden, Daniel G., Sasaki, Makoto
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2575246/
https://ncbi.nlm.nih.gov/pubmed/17177450
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja066772y
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