Spectroscopic and Electronic Structure Studies of Intermediate X in Ribonucleotide Reductase R2 and Two Variants: A Description of the Fe(IV)-Oxo Bond in the Fe(III)-O-Fe(IV) Dimer

Spectroscopic and electronic structure studies of the class I Escherichia coli ribonucleotide reductase (RNR) intermediate X and three computationally-derived model complexes are presented, compared and evaluated to determine the electronic and geometric structure of the Fe(III)-Fe(IV) active site o...

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Hauptverfasser: Mití, Nataša, Clay, Michael D., Saleh, Lana, Bollinger, J. Martin, Solomon, Edward I.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2007
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2565590/
https://ncbi.nlm.nih.gov/pubmed/17602477
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja070909i
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