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Palladium Asymmetric Allylic Alkylation of Prochiral Nucleophiles: Horsfiline
[Image: see text] The asymmetric synthesis of the oxindole alkaloid horsfiline is described. A palladium-catalyzed asymmetric allylic alkylation (AAA) is used to set the spiro(pyrrolidine-oxindole) stereogenic center.
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2006
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2565574/ https://ncbi.nlm.nih.gov/pubmed/16671773 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol060298j |
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