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Synthesis of 3-Iodoindoles by the Pd/Cu-Catalyzed Coupling of N,N-Dialkyl-2-iodoanilines and Terminal Acetylenes, Followed by Electrophilic Cyclization
3-Iodoindoles have been prepared in excellent yields by coupling terminal acetylenes with N,N-dialkyl-o-iodoanilines in the presence of a Pd/Cu catalyst and subsequent electrophilic cyclization of the resulting N,N-dialkyl-o-(1-alkynyl)anilines using I(2) in CH(2)Cl(2). Aryl-, vinylic-, alkyl- and s...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2006
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2556959/ https://ncbi.nlm.nih.gov/pubmed/16388618 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo051549p |
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