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X-ray Absorption Edge Spectroscopy and Computational Studies on LCuO(2) Species: Superoxide-Cu(II) versus Peroxide-Cu(III) Bonding
The geometric and electronic structures of two mononuclear CuO(2) complexes [Cu(O(2)){HB(3-Ad-5-(i)Prpz)(3)}] (1) and [Cu(O(2))(β-diketiminate)] (2) have been evaluated using Cu K- and L- edge X-ray absorption spectroscopy studies in combination with valence bond configuration interaction (VBCI) sim...
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| Autors principals: | , , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2006
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2556900/ https://ncbi.nlm.nih.gov/pubmed/16787093 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0615223 |
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