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X-ray Absorption Edge Spectroscopy and Computational Studies on LCuO(2) Species: Superoxide-Cu(II) versus Peroxide-Cu(III) Bonding

The geometric and electronic structures of two mononuclear CuO(2) complexes [Cu(O(2)){HB(3-Ad-5-(i)Prpz)(3)}] (1) and [Cu(O(2))(β-diketiminate)] (2) have been evaluated using Cu K- and L- edge X-ray absorption spectroscopy studies in combination with valence bond configuration interaction (VBCI) sim...

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Bibliografische gegevens
Hoofdauteurs: Sarangi, Ritimukta, Aboelella, Nermeen, Fujisawa, Kiyoshi, Tolman, William B., Hedman, Britt, Hodgson, Keith O., Solomon, Edward I.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2006
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2556900/
https://ncbi.nlm.nih.gov/pubmed/16787093
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0615223
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