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Total Synthesis of (±)-Bipinnatin J
[Image: see text] The total synthesis of (±)-bipinnatin J was achieved through a concise route that features the use of a silver ion promoted S(N)1-type γ-alkylation of a siloxyfuran and a diastereoselective Cr(II)-mediated macrocyclization to provide bipinnatin J (1), wherein the remote furanone st...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2006
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2537461/ https://ncbi.nlm.nih.gov/pubmed/16435880 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol053054s |
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