Total Syntheses of (−)-α-Kainic Acid and (+)-α-Allokainic Acid via Stereoselective C-H Insertion and Efficient 3,4-Stereocontrol

Reported herein is a novel approach to the total syntheses of (−)-α-kainic acid and (+)-α-allokainic acid, where the stereochemistries on C(2), C(3), and C(4) of the pyrrolidine core were introduced efficiently and selectively. A regio- and stereoselective C-H insertion reaction was utilized to prep...

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Bibliographic Details
Main Authors: Jung, Young Chun, Yoon, Cheol Hwan, Turos, Edward, Yoo, Kyung Soo, Jung, Kyung Woon
Format: Artigo
Language:Inglês
Published: 2007
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2536682/
https://ncbi.nlm.nih.gov/pubmed/18044924
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo701988j
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