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Total Syntheses of (−)-α-Kainic Acid and (+)-α-Allokainic Acid via Stereoselective C-H Insertion and Efficient 3,4-Stereocontrol
Reported herein is a novel approach to the total syntheses of (−)-α-kainic acid and (+)-α-allokainic acid, where the stereochemistries on C(2), C(3), and C(4) of the pyrrolidine core were introduced efficiently and selectively. A regio- and stereoselective C-H insertion reaction was utilized to prep...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2536682/ https://ncbi.nlm.nih.gov/pubmed/18044924 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo701988j |
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