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Iron in the Service of Chromium – the ortho-Benzannulation of trans, trans-Dienyl Fischer Carbene Complexes

Chromium Fischer carbene complexes with trans, trans-dienyl substituents on the carbene carbon will react with diiron nonacarbonyl to give 2-alkoxycyclohexa-2,4-dienone iron tricarbonyl complexes and/or 2-alkoxyphenols in excellent yields. In the presence of silica gel or base, the cyclohexadienone...

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Detalhes bibliográficos
Main Authors: Lian, Yiqian, Wulff, William D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2005
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2535899/
https://ncbi.nlm.nih.gov/pubmed/16332045
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0540268
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