Coupling of Fischer carbene complexes with conjugated enediynes featuring radical traps; Novel structure and reactivity features of chromium complexed arene diradical species

The reaction of Fischer carbene complexes with conjugated enediynes that feature a pendant alkene group has been examined. The reaction proceeds through carbene-alkyne coupling to generate an enyne-ketene intermediate. This intermediate then undergoes Moore cyclization to generate a chromium complex...

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Main Authors: Zhang, Yi, Irshaidat, Tareq, Wang, Haixia, Waynant, Kris V., Wang, Haobin, Herndon, James W.
Formato: Artigo
Idioma:Inglês
Publicado: 2008
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2598427/
https://ncbi.nlm.nih.gov/pubmed/19838290
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jorganchem.2008.08.003
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