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Metal Coordination-Directed Hydroxylation of Steroids with a Novel Artificial P-450 Catalyst

[Image: see text] A novel catalyst has been synthesized in which a manganese–porphyrin unit is linked to two 2,2′-bipyridyl groups and two pentafluorophenyl groups in trans fashion on its four meso positions. Relative to a previous catalyst in which the manganese–porphyrin had four 2,2′-bipyridyl gr...

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Detalhes bibliográficos
Main Authors: Fang, Zhenglai, Breslow, Ronald
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2533127/
https://ncbi.nlm.nih.gov/pubmed/16408887
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol052589i
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