Reversible NO Motion in Crystalline [Fe(Porph)(1-MeIm)(NO)] Derivatives

The synthesis, characterization, and X-ray structures of three low-spin (nitrosyl)iron(II) tetraarylporphyrinates, [Fe(TpXPP)(NO)(1-MeIm)], where X = F (in a triclinic and a monoclinic form) and OCH(3) are reported. All three molecules, at 100 K, have a single orientation of NO. These structures are...

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Hlavní autoři: Silvernail, Nathan J., Pavlik, Jeffrey W., Noll, Bruce C., Schulz, Charles E., Scheidt, W. Robert
Médium: Artigo
Jazyk:Inglês
Vydáno: 2008
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2533045/
https://ncbi.nlm.nih.gov/pubmed/18173262
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic701700p
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