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Reversible NO Motion in Crystalline [Fe(Porph)(1-MeIm)(NO)] Derivatives
The synthesis, characterization, and X-ray structures of three low-spin (nitrosyl)iron(II) tetraarylporphyrinates, [Fe(TpXPP)(NO)(1-MeIm)], where X = F (in a triclinic and a monoclinic form) and OCH(3) are reported. All three molecules, at 100 K, have a single orientation of NO. These structures are...
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| Hauptverfasser: | , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2008
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2533045/ https://ncbi.nlm.nih.gov/pubmed/18173262 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic701700p |
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