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Heme Carbonyls: Environmental Effects on ν(C–O) and Fe–C/C–O Bond Length Correlations

The synthesis and characterization of four low-spin (carbonyl)iron(II) tetraphenylporphyrinates, [Fe(TPP)(CO)(L)], where L = 1-methylimidazole, 2-methylimidazole, 1,2-dimethylimidazole (unsolvated) and 1,2-dimethylimidazole (toluene solvate) are reported. The complexes show nearly the same value of...

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Bibliografische gegevens
Hoofdauteurs: Silvernail, Nathan J., Roth, Arne, Noll, Bruce C., Scheidt, W. Robert, Schulz, Charles E.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2005
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC1866288/
https://ncbi.nlm.nih.gov/pubmed/16218637
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja053148x
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