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Heme Carbonyls: Environmental Effects on ν(C–O) and Fe–C/C–O Bond Length Correlations
The synthesis and characterization of four low-spin (carbonyl)iron(II) tetraphenylporphyrinates, [Fe(TPP)(CO)(L)], where L = 1-methylimidazole, 2-methylimidazole, 1,2-dimethylimidazole (unsolvated) and 1,2-dimethylimidazole (toluene solvate) are reported. The complexes show nearly the same value of...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1866288/ https://ncbi.nlm.nih.gov/pubmed/16218637 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja053148x |
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