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Coordination of Diatomic Ligands to Heme: Simply CO
The synthesis and molecular structures of three iron(II) porphyrinates with only CO as the axial ligand(s) are reported. Two five-coordinate [Fe(OEP)(CO)] derivatives have Fe–C = 1.7077 (13) and 1.7140 (10) Å, much shorter than those of six-coordinate [Fe(OEP)(Im)(CO)], although ν(C-O) is 1944–1948...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1586066/ https://ncbi.nlm.nih.gov/pubmed/16933901 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic0613356 |
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