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Alkyne Hydrosilylation Catalyzed by a Cationic Ruthenium Complex: Efficient and General Trans Addition
The complex [Cp*Ru(MeCN)(3)]PF(6) is shown to catalyze the hydrosilylation of a wide range of alkynes. Terminal alkynes afford access to α-vinylsilane products with good regioselectivity. Deuterium labeling studies indicate a clean trans addition process is at work. The same complex is active in int...
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| Main Authors: | , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2005
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2532823/ https://ncbi.nlm.nih.gov/pubmed/16351094 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0528580 |
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