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An Alkyne Hydrosilylation-Oxidation Strategy for the Selective Installation of Oxygen Functionality
Alkynes bearing propargylic, homopropargylic, and bis-homopropargylic hydroxyl groups are shown to serve as precursors for ketone or α-hydroxy ketone functionality. The approach hinges on the intermediacy of vinylsilanes created through regioselective hydrosilylation catalyzed by the complex [Cp*Ru(...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2581901/ https://ncbi.nlm.nih.gov/pubmed/16011365 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja051578h |
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