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Hydrogen Bonding Catalysis Operates by Charge Stabilization in Highly Polar Diels–Alder Reactions
The alcohol-catalyzed Diels-Alder reactions of acrolein and benzaldehyde with Rawal’s diene were evaluated with density functional theory (B3LYP/6-31G(d)). Several potential modes of catalysis with two methanol molecules were used to model catalysis by TADDOLs. In agreement with crystallographic dat...
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| Główni autorzy: | , , , |
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| Format: | Artigo |
| Język: | Inglês |
| Wydane: |
2007
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| Hasła przedmiotowe: | |
| Dostęp online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2531143/ https://ncbi.nlm.nih.gov/pubmed/17249797 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0629925 |
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