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Total Synthesis of (±)-Symbioimine
[Image: see text] The synthesis of (±)-symbioimine (1) has been completed in only 12 linear steps in 8% overall yield. The key step is the treatment of 13b with BF(3)•Et(2)O to generate N-carboalkoxydihydropyridinium cation 14b, which undergoes a novel sterospecific intramolecular Diels-Alder reacti...
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2006
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2529459/ https://ncbi.nlm.nih.gov/pubmed/17107083 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol062333s |
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