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Regiochemical Control in the Metal-Catalyzed Transposition of Allylic Silyl Ethers
A novel mode of regiochemical control over the allylic [1,3]-transposition of silyloxy groups catalyzed by Re(2)O(7) has been developed. This strategy relies on a cis-oriented vinyl boronate, generated from the Alder ene reaction of homoallylic silyl ethers and alkynyl boronates, to trap out the all...
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| Huvudupphovsmän: | , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2006
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2528283/ https://ncbi.nlm.nih.gov/pubmed/16787071 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0620639 |
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