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Studies on a Total Synthesis of the Microbial Immunosuppresive Agent FR901483

A strategy is outlined for construction of the fungal immunosuppressant FR901483 (1). It was possible to convert 1,4-cyclohexanedione monoethylene ketal in five simple steps to iodoacetamide ketone 10, which was cyclized in good yield to the key bridged keto lactam 11 containing the A/B 2-azabicyclo...

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Detalhes bibliográficos
Main Authors: Kropf, Jeffrey E., Meigh, Ivona C., Bebbington, Magnus W.P., Weinreb, Steven M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2527037/
https://ncbi.nlm.nih.gov/pubmed/16496992
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo052466b
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