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Gold-Catalyzed 1,2-Migration of Silicon, Tin, and Germanium en route to C-2 Substituted Fused Pyrrole-Containing Heterocycles
An efficient method for the synthesis of fused pyrroloheterocycles from diverse propargyl-substituted heterocycles in the presence of Au-catalyst has been developed. The cascade transformation proceeds via alkyne-vinylidene isomerization with concomitant 1,2-shift of hydrogen, silyl and stannyl grou...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2006
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2523260/ https://ncbi.nlm.nih.gov/pubmed/16967938 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja063278l |
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