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Dynamics of ligand substitution in labile cobalt complexes resolved by ultrafast T-jump
Ligand exchange of hydrated metal complexes is common in chemical and biological systems. Using the ultrafast T-jump, we examined this process, specifically the transformation of aqua cobalt (II) complexes to their fully halogenated species. The results reveal a stepwise mechanism with time scales v...
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| Main Authors: | , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
National Academy of Sciences
2008
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2522261/ https://ncbi.nlm.nih.gov/pubmed/18725628 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0806869105 |
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