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Dynamics of ligand substitution in labile cobalt complexes resolved by ultrafast T-jump

Ligand exchange of hydrated metal complexes is common in chemical and biological systems. Using the ultrafast T-jump, we examined this process, specifically the transformation of aqua cobalt (II) complexes to their fully halogenated species. The results reveal a stepwise mechanism with time scales v...

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Detaylı Bibliyografya
Asıl Yazarlar: Ma, Hairong, Wan, Chaozhi, Zewail, Ahmed H.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: National Academy of Sciences 2008
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC2522261/
https://ncbi.nlm.nih.gov/pubmed/18725628
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0806869105
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