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Highly Cooperative Tetrametallic Ruthenium-μ-Oxo-μ-Hydroxo Catalyst for the Alcohol Oxidation Reaction

The tetrametallic ruthenium-oxo-hydroxo-hydride complex {[(PCy(3))(CO)RuH](4)(μ(4)-O)(μ(3)-OH)(μ(2)-OH)} (1) was synthesized in two steps from the monomeric complex (PCy(3))(CO)RuHCl (2). The tetrameric complex 1 was found to be a highly effective catalyst for the transfer dehydrogenation of alcohol...

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Detalhes bibliográficos
Main Authors: Yi, Chae S., Zeczycki, Tonya N., Guzei, Ilia A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2519863/
https://ncbi.nlm.nih.gov/pubmed/18726005
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om0510674
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